Contributors: EPSRC, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM
Subject Terms: α,β-unsaturated acyl ammonium, Palladium catalysis, Isothiourea, Cycloaddition, Cooperative catalysis, QD Chemistry, DAS, QD
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Relation: Angewandte Chemie International Edition; Bitai , J , Nimmo , A , Slawin , A M Z & Smith , A D 2022 , ' Cooperative palladium/isothiourea catalyzed enantioselective formal (3+2) cycloaddition of vinylcyclopropanes and α,β-unsaturated esters ' , Angewandte Chemie International Edition , vol. 61 , no. 25 , e202202621 . https://doi.org/10.1002/anie.202202621; PURE: 278794356; PURE UUID: aa2c7395-d4ed-4275-a55e-230ed0a314b3; ORCID: /0000-0002-2104-7313/work/112333090; ORCID: /0000-0002-9527-6418/work/112333135; Scopus: 85128933445; WOS: 000788376400001; http://hdl.handle.net/10023/25270; https://doi.org/10.1002/anie.202202621; EP/L016419/1
Authors: Arokianathar, Jude N., Hartley, Will, McLaughlin, Calum, Greenhalgh, Mark David, Stead, Darren, Ng, Sean, Slawin, Alexandra Martha Zoya, Smith, Andrew David
Contributors: European Commission, The Royal Society, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM
Subject Terms: Isothiourea, Ammonium enolate, Ayloxide, Quinone methide, Ester functionalization, 1,6-conjugate addition, QD Chemistry, DAS, QD
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Relation: Molecules; Arokianathar , J N , Hartley , W , McLaughlin , C , Greenhalgh , M D , Stead , D , Ng , S , Slawin , A M Z & Smith , A D 2021 , ' Isothiourea-catalyzed enantioselective α-alkylation of esters via 1,6-conjugate addition to para -quinone methides ' , Molecules , vol. 26 , no. 21 , 6333 . https://doi.org/10.3390/molecules26216333; PURE: 276279349; PURE UUID: f0fc5383-5d49-48cf-a0c1-31b374eb292c; ORCID: /0000-0002-2104-7313/work/101958330; ORCID: /0000-0002-9527-6418/work/101958403; Scopus: 85117896690; WOS: 000723136400001; http://hdl.handle.net/10023/24172; https://doi.org/10.3390/molecules26216333; https://www.mdpi.com/1420-3049/26/21/6333; https://www.mdpi.com/journal/molecules/special_issues/Alexandra_Slawin; N/A; WM140071
Authors: McLaughlin, Calum, Smith, Andrew D.
Contributors: The Royal Society, University of St Andrews. University of St Andrews, University of St Andrews. School of Chemistry
Subject Terms: Aryloxides, C(1)-ammonium enolates, Catalyst turnover, Formal cycloaddition, Isothioureas, QD Chemistry, QD
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Relation: Chemistry - A European Journal; McLaughlin , C & Smith , A D 2020 , ' Generation and reactivity of C(1)-ammonium enolates using isothiourea catalysis ' , Chemistry - A European Journal , vol. Early View . https://doi.org/10.1002/chem.202002059; PURE: 268566064; PURE UUID: 23705d8a-707e-4f76-ba71-16528e4c5a21; WOS: 000587734000001; Scopus: 85096780741; http://hdl.handle.net/10023/20941; https://doi.org/10.1002/chem.202002059; WM140071
Authors: Matviitsuk, Anastassia, Greenhalgh, Mark, Barrios Antunez, Diego, Slawin, Alexandra, Smith, Andrew David
Contributors: EPSRC, European Commission, The Royal Society, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM, University of St Andrews. Biomedical Sciences Research Complex
Subject Terms: Lewis base catalysis, α,β-unsaturated ammonium, Isothiourea, Aryloxide catalyst turnover, Kinetic and mechanistic analysis, QD Chemistry, DAS, BDC, R2C, QD
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Relation: Angewandte Chemie; Matviitsuk , A , Greenhalgh , M , Barrios Antunez , D , Slawin , A & Smith , A D 2017 , ' Aryloxide-facilitated catalyst turnover in enantioselective α,β-unsaturated acyl ammonium catalysis ' , Angewandte Chemie , vol. 129 , no. 40 , pp. 12450-12455 . https://doi.org/10.1002/ange.201706402; PURE: 250595435; PURE UUID: 07e80960-f055-4c13-b392-dc46550a29a8; Scopus: 85028361613; ORCID: /0000-0002-2104-7313/work/36567474; ORCID: /0000-0002-9527-6418/work/56861809; http://hdl.handle.net/10023/11551; https://doi.org/10.1002/ange.201706402; EP/J018139/1; N/A; WM140071
Authors: Matviitsuk, Anastassia, Taylor, James Edward, Cordes, David Bradford, Slawin, Alexandra Martha Zoya, Smith, Andrew David
Contributors: EPSRC, The Royal Society, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM, University of St Andrews. Biomedical Sciences Research Complex
Subject Terms: Domino reactions, Enantioselective synthesis, Lewis base, Organocatalysis, α,β-unsaturated acyl ammonium, QD Chemistry, A General Works, DAS, QD
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Relation: Chemistry - A European Journal; Matviitsuk , A , Taylor , J E , Cordes , D B , Slawin , A M Z & Smith , A D 2016 , ' Enantioselective stereodivergent nucleophile-dependent isothiourea-catalysed domino reactions ' , Chemistry - A European Journal , vol. 22 , no. 49 , pp. 17748-17757 . https://doi.org/10.1002/chem.201603318; PURE: 245237155; PURE UUID: 7cab6d38-0ff6-4470-8799-cda59ad142da; WOS: 000388471700032; Scopus: 84991080752; ORCID: /0000-0002-2104-7313/work/36567482; ORCID: /0000-0002-5366-9168/work/28023968; ORCID: /0000-0002-9527-6418/work/56861553; http://hdl.handle.net/10023/9649; https://doi.org/10.1002/chem.201603318; EP/J018139/1; WM140071
Contributors: University of St Andrews. School of Earth & Environmental Sciences, University of St Andrews. St Andrews Centre for Exoplanet Science, University of St Andrews. Scottish Oceans Institute, University of St Andrews. St Andrews Sustainability Institute, University of St Andrews. St Andrews Isotope Geochemistry, University of St Andrews. Marine Alliance for Science & Technology Scotland
Subject Terms: Nitrogen isotopes, Paleozoic nitrogen cycling, Abiogenic carbonate storage, Ammonium migration, Nitrogen in clay, GE Environmental Sciences, DAS, SDG 13 - Climate Action, SDG 14 - Life Below Water, GE
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Relation: Palaeogeography, Palaeoclimatology, Palaeoecology; Koehler , M C , Stüeken , E E , Hillier , S & Prave , T 2019 , ' Limitation of fixed nitrogen and deepening of the carbonate-compensation depth through the Hirnantian at Dob's Linn, Scotland ' , Palaeogeography, Palaeoclimatology, Palaeoecology , vol. 534 , 109321 . https://doi.org/10.1016/j.palaeo.2019.109321; PURE: 260662750; PURE UUID: 092d8b71-c837-424c-bc5d-9c145c36c965; RIS: urn:DE6EB4D568BCE78B0E8E78B90F334AD5; Scopus: 85070873135; ORCID: /0000-0002-4614-3774/work/64033701; ORCID: /0000-0001-6861-2490/work/65014414; WOS: 000504504200018; http://hdl.handle.net/10023/20447; https://doi.org/10.1016/j.palaeo.2019.109321
Authors: Chen, Yan, Diamond, Charles W., Stüeken, Eva E., Cai, Chunfang, Gill, Benjamin C., Zhang, Feifei, Bates, Steve M., Chu, Xuelei, Ding, Yi, Lyons, Timothy W.
Contributors: University of St Andrews. School of Earth & Environmental Sciences, University of St Andrews. St Andrews Centre for Exoplanet Science
Subject Terms: Ediacaran, Cambrian, Yangtze Block, Nitrogen cycling, Redoxcline, Ammonium, GE Environmental Sciences, DAS, GE
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Relation: Geochimica et Cosmochimica Acta; 259078445; 361b2d0d-85f9-441f-a37f-eac757b3c9fa; 85066100614; 000470830800016; Chen , Y , Diamond , C W , Stüeken , E E , Cai , C , Gill , B C , Zhang , F , Bates , S M , Chu , X , Ding , Y & Lyons , T W 2019 , ' Coupled evolution of nitrogen cycling and redoxcline dynamics on the Yangtze Block across the Ediacaran-Cambrian transition ' , Geochimica et Cosmochimica Acta , vol. In press . https://doi.org/10.1016/j.gca.2019.05.017; RIS: urn:235A5CDF6F4C5A5BF8BD12AA47DC26BC; ORCID: /0000-0001-6861-2490/work/65014420; https://hdl.handle.net/10023/19955
Authors: McLaughlin, Calum
Contributors: Smith, Andrew David, Engineering and Physical Sciences Research Council (EPSRC)
Subject Terms: QD505.M3, Organic compounds--Synthesis, Catalysis, Ammonium compounds
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Relation: Enantioselective Isothiourea Catalysis via C(1)-Ammonium Enolate Intermediates: Applications and Mechanistic Studies (Thesis data) McLaughlin, C., University of St Andrews, 8 Dec 2022. DOI: https://doi.org/10.17630/db492d31-bb46-42ad-9953-0251c2245363; https://doi.org/10.17630/db492d31-bb46-42ad-9953-0251c2245363; http://hdl.handle.net/10023/27782; https://doi.org/10.17630/sta/503; EP/M508214/1
Authors: Kasten, Kevin, Slawin, Alexandra M. Z., Smith, Andrew D.
Contributors: European Commission, The Royal Society, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM, University of St Andrews. Biomedical Sciences Research Complex
Subject Terms: Flluorinated amino-acids, Allylic ammonium ylides, Kinetic resolution, Medicinal chemistry, Protein design, Catalysts, Mannich, Benzotetramisole, Straightforward, Cycloaddition, QD Chemistry, DAS, QD
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Relation: Organic Letters; Kasten , K , Slawin , A M Z & Smith , A D 2017 , ' Enantioselective synthesis of β-fluoro-β-aryl-α-amino pentenamides by organocatalytic [2,3]-sigmatropic rearrangement ' , Organic Letters , vol. 19 , no. 19 , pp. 5182-5185 . https://doi.org/10.1021/acs.orglett.7b02452; PURE: 250962719; PURE UUID: 07670065-865e-41af-9c62-6aebd918224a; WOS: 000412789600045; Scopus: 85032614861; ORCID: /0000-0002-2104-7313/work/37255560; ORCID: /0000-0002-9527-6418/work/56861707; http://hdl.handle.net/10023/15992; https://doi.org/10.1021/acs.orglett.7b02452; N/A; WM140071
Contributors: European Commission, The Royal Society, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM, University of St Andrews. Biomedical Sciences Research Complex
Subject Terms: [2,3]-rearrangement, Isothiourea catalysis, Allylic ammonium ylides, Enantioselective catalysis, α-amino esters, QD Chemistry, DAS, QD
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Relation: Tetrahedron; West , T H , Spoehrle , S S M & Smith , A D 2017 , ' Isothiourea-catalysed chemo- and enantioselective [2,3]-sigmatropic rearrangements of N , N -diallyl allylic ammonium ylides ' , Tetrahedron , vol. 73 , no. 29 , pp. 4138-4149 . https://doi.org/10.1016/j.tet.2017.01.062; PURE: 249036825; PURE UUID: ff39a291-b4c9-4ddc-9455-46f06d19a635; RIS: urn:0E61E9C036C60511338C857E4F9FD3AF; Scopus: 85013441087; ORCID: /0000-0002-2104-7313/work/36567476; WOS: 000405158400015; http://hdl.handle.net/10023/12636; https://doi.org/10.1016/j.tet.2017.01.062; http://www.sciencedirect.com/science/article/pii/S0040402017300972#appd001; SUBICAT; WM140071; N/A
Contributors: EPSRC, University of St Andrews. School of Chemistry, University of St Andrews. Biomedical Sciences Research Complex, University of St Andrews. EaSTCHEM
Subject Terms: Lewis base catalysis, α,β-unsaturated acyl ammonium intermediates, Isothiourea catalysis, Cascades, Enantioselective catalysis, QD Chemistry, NDAS, QD
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Relation: Synthesis; Robinson , E R T , Frost , A B , Elías-Rodríguez , P & Smith , A D 2017 , ' Enantioselective isothiourea catalysed Michael-Michael-lactonisation cascade; synthesis of δ-lactones and 1,2,3,4-substituted cyclopentanes ' , Synthesis , vol. 49 , no. 2 , pp. 409-423 . https://doi.org/10.1055/s-0036-1588636; PURE: 246625917; PURE UUID: 1f69a36f-f906-4e2a-80bf-68e9cc86e8b1; Scopus: 84996805889; ORCID: /0000-0002-2104-7313/work/36567484; WOS: 000393232500021; http://hdl.handle.net/10023/12163; https://doi.org/10.1055/s-0036-1588636; EP/J018139/1
Authors: West, Thomas Henry, Spoehrle, Stephanie Suzanne Madeleine, Kasten, Kevin, Taylor, James Edward, Smith, Andrew David
Contributors: Marie Curie Fellowships, The Royal Society, University of St Andrews. School of Chemistry, University of St Andrews. Biomedical Sciences Research Complex, University of St Andrews. EaSTCHEM
Subject Terms: Stereoselective catalysis, [2,3]-rearrangement, Allylic oxonium ylides, Allylic ammonium ylides, O-propargylic oximes, Allylic sulfoxides, Allylic N-oxides, QD Chemistry, NDAS, QD
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Relation: ACS Catalysis; West , T H , Spoehrle , S S M , Kasten , K , Taylor , J E & Smith , A D 2015 , ' Catalytic stereoselective [2,3]-rearrangement reactions ' , ACS Catalysis , vol. In press . https://doi.org/10.1021/acscatal.5b02070; PURE: 228188234; PURE UUID: a4851398-1b1a-4731-ae2d-a38bb03a5a21; Scopus: 84948845064; ORCID: /0000-0002-2104-7313/work/36567496; WOS: 000366153300045; http://hdl.handle.net/10023/9734; https://doi.org/10.1021/acscatal.5b02070; SUBICAT
Contributors: University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM
Subject Terms: Woollins' reagent, Amines, Ammonium phenylphosphonamidodiselenoates, Phenylphosphonamidodiselenoic diamides, X-ray diffraction, Phosphor-1,1-dithiolato metal-complexes, Supramolecular associations, Coordination chemistry, Stereochemical aspects, Molecular-structures, Organic-synthesis, Selenium, Organoselenium, Patterns, QD Chemistry, QD
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Relation: Zeitschrift für Anorganische und Allgemeine Chemie; Hua , G , Randall , R A M , Slawin , A M Z & Woollins , J D 2011 , ' Ammonium Phenylphosphonamidodiselenoates and Phenylphosphonamidodi-selenoic Diamides from the Selenation of Primary and Secondary Amines ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 637 , no. 12 , pp. 1800-1806 . https://doi.org/10.1002/zaac.201100257; PURE: 16776620; PURE UUID: a6d60f7c-d97f-47a1-b534-866cc3573f35; WOS: 000296856300023; Scopus: 80054968743; ORCID: /0000-0002-9527-6418/work/56861349; ORCID: /0000-0002-1498-9652/work/31779227; http://hdl.handle.net/10023/5099; https://doi.org/10.1002/zaac.201100257
Authors: Robinson, Emily R. T.
Contributors: Smith, Andrew David, Engineering and Physical Sciences Research Council (EPSRC)
Subject Terms: Organocatalysis, Catalysis, Michael addition, Asymmetric, α,β-unsaturated acyl ammonium, QD505.R74, Asymmetric synthesis, Organic compounds--Synthesis, Ammonium compounds
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Relation: http://hdl.handle.net/10023/7010
Availability: http://hdl.handle.net/10023/7010
